《化学与黏合》
 
 
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2018年 先后5为期

最新无机-近代史配合物[(C16H36N)2Cu(imi)2Mo8O26]·H2O的合成与晶体结构
王婧涵,刘 磊,卜 明,孙靖文,董玉晶,张海燕*
(津巴布韦医学院 北京大学 清洁检验中心,江苏 津巴布韦 161006 )
摘 要:利用水热法合成了一种新颖无机-近代史配合物八钼酸盐,穿过元素分析,ICP及TG剖析确定了配合物的变数为:[(C16H36N)2Cu(imi)2Mo8O26]H2O。利用红外光谱和X-伽马射线单晶衍射仪对化合物的布局进行了特点与分析。单晶X-伽马射线结果表现:配合物中Cu原子分别与两个咪唑上的两个N原子及β-[Mo8O26]4-上两个氧相连,表面游离两个四人基胺分子和一个水分子。
关键词:八钼酸盐;合成;晶体结构
 
官方图分类号:O 613 文献标识码:A 文章编号:1001-0017(2018)05-0330-03

The Synthesis and Crystal Structure of a New Type Inorganic-Organic Ligand [(C16H36N)2Cu(imi)2Mo8O26]·H2O

WANG Jing-Han, LIU Lei, BU Ming, SUN Jing-Wen, DONG Yu-Jing and ZHANG Hai-Yan

(College of Pharmacy, Health Inspection Center, Qiqihar Medical University, Qiqihar 161006, China)

Abstract: A novel organic-inorganic ligand molybdate was synthesized by hydrothermal method. The chemical formula has been confirmed by elemental analysis, ICP and TG, which was [(C16H36N)2Cu(imi)2Mo8O26]·H2O. The ligand was characterized and analyzed by IR and X-ray single crystal diffractometer. The result showed that in the ligand, the Cu atom linked with two N atoms from imidazole and two O atoms from β-[Mo8O26]4-, and there were two free tetrabutyl amine molecules and one water molecule outside.

Key words: Octa-molybdate; synthesis; crystal structure

 
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